The oxidative acylation reactions proceed with a 1:1 stoichiometry of aldehyde and alcohol (for primary alcohols) with remarkably short residence times in the electrolysis … http://pubs.acs.org/page/copyright/permissions.html, https://doi.org/10.1021/acs.orglett.7b00060, https://doi.org/10.1021/acs.orglett.6b02959, https://doi.org/10.1021/acs.orglett.5b00190, https://doi.org/10.1088/1755-1315/459/3/032011, https://doi.org/10.1016/j.tetlet.2019.151464, https://doi.org/10.1016/j.tetlet.2017.11.002, https://doi.org/10.1134/S1070363216110049, https://doi.org/10.1016/j.tetlet.2016.06.115, https://doi.org/10.1007/s11164-015-2408-4, https://doi.org/10.1016/j.tet.2014.05.017, https://doi.org/10.3184/174751914X14031774189763. The Project of National First-Class Disciplines (PNFD). This material is available free of charge via the Internet at http://pubs.acs.org. Experimental procedures, characterization data, and spectra of the compounds. 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James M. Bobbitt, Ashley L. Bartelson, William F. Bailey, Trevor A. Hamlin, and Christopher B. Kelly . The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Tropolonate Salts as Acyl-Transfer Catalysts under Thermal and Photochemical Conditions: Reaction Scope and Mechanistic Insights. Electronic Supporting Information files are available without a subscription to ACS Web Editions. Information about how to use the RightsLink permission system can be found at Find more information on the Altmetric Attention Score and how the score is calculated. Oxidation of alcohols using an oxoammonium salt bearing the nitrate anion. Get article recommendations from ACS based on references in your Mendeley library. V. P. Kashparova, I. S. Kashparov, I. Yu. This is a preview of subscription content, log in to check access. Access to Nitriles from Aldehydes Mediated by an Oxoammonium Salt. You have to login with your ACS ID befor you can login with your Mendeley account. A simple, high yielding, rapid route for the oxidative esterification of a wide range aldehydes to hexafluoroisopropyl (HFIP) esters using the oxoammonium salt 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1a) is reported. without permission from the American Chemical Society. A Cu-catalyzed practical approach to α-ketoesters under air: an efficient aerobic oxidative dehydrogenative coupling of alcohols and α-carbonyl aldehydes. Files available from the ACS website may be downloaded for personal use only. Yuhan Zhou, Dongmei Yang, Gen Luo, Yilong Zhao, Yi Luo, Na Xue, Jingping Qu. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Suman Pramanik, Reddy Rajasekhar Reddy, and Prasanta Ghorai . http://pubs.acs.org/page/copyright/permissions.html. Zhukova, A. V. Astakhov, I. The research was supported by the National Natural Science Foundation of China (No. Oxoammonium salt-mediated oxidative nitriles synthesis from aldehydes with ammonium acetate. 3 This article is cited by The chemical shifts of the characteristic proton of C2 on the imidazolium ring (N−C=N) were discussed thoroughly and all of these imidazolium salts exhibit good thermal stability. An efficient N-heterocyclic carbene (NHC)-mediated oxidative esterification of aldehydes in an undivided microfluidic electrolysis cell provides up to 4.3 g h-1 of product in a single pass with excellent yields at ambient temperature. Accessing N-Acyl Azoles via Oxoammonium Salt-Mediated Oxidative Amidation. A simple, one-pot oxidative esterification of aryl aldehydes through dialkyl acetal using hydrogen peroxide. Oxidative Esterification of Aldehydes Using a Recyclable Oxoammonium Salt, Department of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, Connecticut 06269-3060, United States, and Department of Community Medicine & Health Care, University of Connecticut Health Center, The Exchange, 263 Farmington Avenue, Farmington, Connecticut 06030, United States. PubMed Central  2-Iodoxybenzenesulfonic Acid-Catalysed oxidation of Primary and Secondary Alcohols with Oxone in Cetyl Trimethylammonium Bromide Micelles at Room Temperature. Below is the link to the electronic supplementary material. Anirban Mukherjee, Arshad J. Ansari, S. Rajagopala Reddy, Gourab Kanti Das, Ritesh Singh. These metrics are regularly updated to reflect usage leading up to the last few days. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting PubMed Google Scholar. B. Ilchibaeva, E. Sh. Intramolecular Rearrangement of α-Azidoperoxides: An Efficient Synthesis of tert-Butyl Esters. John M. Ovian, Christopher B. Kelly, Vincent A. Pistritto, and Nicholas E. Leadbeater . Find more information about Crossref citation counts. Shifa Wang. Jacob. A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations. Sixteen new camphor-based imidazolium salts have been synthesized with renewable camphorsulfonic acid as the starting material. Oxidative Esterification of Aldehydes and Alcohols Catalyzed by Camphor-Based Imidazolium Salts.

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